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Preconditions:
The objective of the purifying plant in Göttingen is the removal and
reclaiming of ammonium from filtrate water according to the latest
scientific techniques. Otherwise, the municipality would not be able to
fulfill the minimum legal requirements. Especially the high component of
nitrogen in Göttingen's drainage water was an unusual difficulty here for a
purely biological cleaning procedure. But after successful pre-trials, it
was decided to find a process that should not only be economically
attractive, but which could also be meaningfully integrated in the existing
plant technology. The final objective was, in addition, the manufacture of a
still-to-be-marketed product that resulted from the eliminated nitrogen.
Concept:
The method of air stripping followed by an "acid scrubber" was
determined to be an economically cost-effective process for the special
boundary conditions for the purifying plant at Göttingen. Of particular
advantage here is the lime conditioning of the sludge that is carried out
before drainage, which results in an increase in the pH-value in the
filtrate. In addition, the heat emitted was usefully integrated in the heat
circuit of the purifying plant. Another important factor in the process of
awarding the contract was that a guaranteed take-up of the ammonium sulfate
over a period of 10 years was required and offered. This gave Göttingen's
city water treatment facility the highest possible cost safety in addition
to maximum operational guarantee. Therefore, particularly when calling for
tenders, attention was paid to the construction and the subsequent running
of operations as mentioned above.
Technology:
The process and plant engineering is distinguished by the following
points:
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The chamber filter press generates the filtrate
water in single-shift operation.
At a rated volume flow of 17-20 m³/h,
the filtrate water is stored temporarily in steel-enameled tanks.
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After the withdrawal of the medium from the storage
tanks, the pH-value can be increased with caustic soda if required, By
using internal sources such as the waste heat from the return water, the
temperature of the filtrate water increases.
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In a stripping column, the ammonia present in the
filtrate water is then driven out with circulating air.
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The concentration of ammonium is now reduced in one
process step to below
100 mg/l. The stripping efficiency in trial runs
after removal of pure water and the residual heat was more than 95 %.
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The purified air is returned back to the stripping
column. A closed air circuit is thus guaranteed.
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The tower packing piling, in this case, in the
stripping column and absorption column facilitate a large phase contact
surface area, which favors the material exchange. Rauschert Hiflow-Rings
are used as the tower packings. Their open grid structure makes them
resistant to dirt. Other advantages are low weight, high loading
capacity and mechanical strength. The low pressure loss saves on blower
power.
Result:
The ammonium sulfate solution that results can be used as a type-approved
fluid manure in agriculture or horticulture. Alternatively, the process
product can be used in the leather industry, the wood-processing industry
and for the smothering of furnaces and cement works.
Owing to the reclaiming
of ammonium, the primary requirement of the Kreislaufwirtschafts- und
Abfallgesetz (German pollution law) is fulfilled: no waste is generated at
all.
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